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Raw palygorskite was modified by the addition of selected surfactants, viz. hexadecyltrimethylammonium bromide (CTAB), cetylpyridinium bromide (CPB) and octadecyldimethylbenzyl ammonium chloride (ODBA...
A thermodynamic model of non-convergent cation-ordering in karrooite (MgTi O ) has been cali-2 5 brated from the single-crystal X-ray structure refinements of Yang and Hazen (1998) and from esti- ma...
Thetemperaturedependenceofthecationdistributioninsyntheticspinel(MgAl O )was2 4 determinedusingin-situtime-of-?ightneutronpowderdiffraction.Neutrondiffractionpat- ternsofstoichiometricMgAl O andsli...
Inathermodynamicdescriptionofamineralsolidsolution,itiscustomarytoselecta minimalgroupofend-membersthatconstitutesanindependentset,andyetinpractical calculationsitcommonlyoccursthatadifferentindepen...
The thermodynamics of order-disorder in mineral solid solutions are handled withsym-metric formalism, whereby the mineral is treated as a solid solution between an indepen-dent set of end-members with...
Thermodynamics of order-disorder in minerals maybe approached by treating the min-eral as a solid solution between an independent set of end-members withwhich the range of possible states of ordering ...
The integral thermodynamic quantities of adsorbed water on Na- and Ca-montmorillonite have been calculated from water adsorption isotherms on Na- and Ca-montmorillonite at 298° and 313°K and from one ...
Abstract: A thermodynamic study has been made of the ion exchange equilibria of the n-alkylammonium ions in sodium montmorillonite. Exchange isotherms of ammonium, methylammonium, ethylammonium, propy...

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