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A detailed full-chemistry 3-D chemistry and transport model (CTM) is used to evaluate the current stratospheric O3 parameterisation in the European Centre for Medium-Range Weather Forecasts (ECMWF) mo...
The heterogeneous reactions of carbonyl sulfide (OCS) on the typical mineral oxides in the mineral dust particles were investigated using a Knudsen cell flow reactor and a diffuse reflectance UV-vis s...
This article, the fifth in the ACP journal series, presents data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the heterogeneous processes on ...
The heterogeneous ice nucleation potential of airborne oxalic acid dihydrate and sodium oxalate particles in the deposition and condensation mode has been investigated by controlled expansion cooling ...
A study of the atmospheric heterogeneous reactions of formic acid, acetic acid, and propionic acid on α-Al2O3 was performed at ambient condition by using a diffuse reflectance infrared Fourier transfo...
The first direct laboratory measurements of gaseous hydrogen peroxide uptake by authentic Gobi and Saharan dust aerosol particles as a function of relative humidity (RH) have been carried out in an en...
The heterogeneous oxidation of laboratory Secondary Organic Aerosol (SOA) particles by OH radicals was investigated. SOA particles, produced by reaction of α-pinene and O3, were exposed to OH radicals...
During the measurement campaign FROST (FReezing Of duST), LACIS (Leipzig Aerosol Cloud Interaction Simulator) was used to investigate the immersion freezing behavior of size selected, coated and uncoa...
All samples were observed to initiate ice formation via the deposition mode at threshold ice super-saturations (RHithresh) ranging from 105% to 140% for temperatures below 220 K. Approximately 10% of ...
With increasing NO2 concentration in the troposphere, the importance of NO2 reaction with mineral dust in the atmosphere needs to be evaluated. Until now, little is known about the reaction of NO2 wit...
This study assesses in detail the effects of heterogeneous chemistry on the particle surface and gas-phase composition by modeling the reversible co-adsorption of O3, NO2, and H2O on soot coated with ...
The sum of peroxy radicals (HO2+ΣiRiO2) and supporting trace gases were measured on the Jungfraujoch (3580 m a.s.l.) during the late summer of 2005. The period was marked by extended times of heavy sn...
The heterogeneous oxidation of SO2 by NO2 on mineral dust was studied using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) and a Knudsen cell. This made it possible to characteri...
Methyl chloroform (1,1,1-trichloroethane, CH3CCl3) was found to decompose heterogeneously on seven types of standard clay minerals (23 materials) in dry air at 313 K in the laboratory. All reactions p...
The heterogeneous freezing temperatures of single binary sulfuric acid solution droplets were measured in dependency of acid concentration down to temperatures as low as -50°C. In order to avoid influ...

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